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Because of the thermoelectric (TE) effect (or Seebeck effect), a difference of potential is generated as a consequence of a temperature gradient across a sample. The TE effect has been mostly studied and engineered in semiconducting materials and it already finds several commercial applications. Only recently the TE effect in cement-based materials has been demonstrated and there is a growing interest in its potential. For instance, a temperature gradient across the external walls of a building can be used to generate electricity. By the inverse of the TE effect (or Peltier effect), one can also seek to control the indoor temperature of a building by biasing TE elements embedded in its external walls. In designing possible applications, the TE properties of cement-based materials must be determined as a function of their chemical composition. For instance, the TE properties of cement paste can be enhanced by the addition of metal oxide (e.g., Fe2O3) powder. In this paper, a single thermoelectric leg is studied using the finite element method. Metal oxide additives in the cement paste are modelled as spherical inhomogeneities. The thermoelectric properties of the single components are based on experimental data, while the overall thermoelectric properties of the composites are obtained from the numerical model. The results of this numerical study are interpreted according to the effective medium theory (EMT) and its generalisation (GEMT). 

Thermoelectric materials enable the direct conversion of thermal energy to electricity. Ambient heat energy harvesting could be an effective route to convert buildings from being energy consumers to energy harvesters, thus making them more sustainable. There exists a relatively stable temperature gradient (storing energy) between the internal and external walls of buildings which can be utilized to generate meaningful energy (that is, electricity) using the thermoelectric principle. This could ultimately help reduce the surface temperatures and energy consumption of buildings, especially in urban areas. In this paper, ongoing work on developing and characterizing a cement-based thermoelectric material is presented. Samples are fabricated using cement as a base material and different metal oxides (Bi₂O₃ and Fe₂O₃) are added to enhance their thermoelectric properties. A series of characterization tests are undertaken on the prepared samples to determine their Seebeck coefficient, electrical and thermal conductivity. The study shows that cement paste with additives possesses physical properties in the range of semiconductors whereby, initially, the resistivity values are low but with time, they increase gradually, thus resulting in lower electrical conductivity. The thermal conductivity of the cement paste with additives is lower than the control sample. Seebeck coefficient values were found to be relatively unstable during the initial set of measurements because the internal and external environment needed to be kept in a thermally stable condition to achieve steady results. The detailed analysis helped determine and eliminate the source of errors in the characterization process and obtain repeatable results. Parameters such as moisture content, temperature, and age were found to have a significant impact on the properties of cement-based thermoelectric materials.